Photo: Liquid crystals dried and viewed through polarized light. You can see they have a much more regular structure than an ordinary liquid. Photo from research by David Weitz courtesy of NASA Marshall Space Flight Center (NASA-MSFC).
We're used to the idea that a given substance can be in one of three states: solid, liquid, or gas—we call them states of matter—and up until the late 19th century, scientists thought that was the end of the story. Then, in 1888, an Austrian chemist named Friedrich Reinitzer (1857–1927) discovered liquid crystals, which are another state entirely, somewhere in between liquids and solids. Liquid crystals might have lingered in obscurity but for the fact that they turned out to have some very useful properties.
Solids are frozen lumps of matter that stay put all by themselves, often with their atoms packed in a neat, regular arrangement called a crystal (or crystalline lattice). Liquids lack the order of solids and, though they stay put if you keep them in a container, they flow relatively easily when you pour them out. Now imagine a substance with some of the order of a solid and some of the fluidity of a liquid. What you have is a liquid crystal—a kind of halfway house in between. At any given moment, liquid crystals can be in one of several possible "substates" (phases) somewhere in a limbo-land between solid and liquid. The two most important liquid crystal phases are called nematic and smectic:
When they're in the nematic phase, liquid crystals are a bit like a liquid: their molecules can move around and shuffle past one another, but they all point in broadly the same direction. They're a bit like matches in a matchbox: you can shake them and move them about but they all keep pointing the same way.
If you cool liquid crystals, they shift over to the smectic phase. Now the molecules form into layers that can slide past one another relatively easily. The molecules in a given layer can move about within it, but they can't and don't move into the other layers (a bit like people working for different companies on particular floors of an office block). There are actually several different smectic "subphases" .
